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Metal Air Batteries: Engineering Catalytic Active Sites on Cobalt Oxide Surface for Enhanced Oxygen Electrocatalysis (Adv. Energy Mater. 10/2018)
Author(s) -
Han Xiaopeng,
He Guowei,
He Yu,
Zhang Jinfeng,
Zheng Xuerong,
Li Lanlan,
Zhong Cheng,
Hu Wenbin,
Deng Yida,
Ma TianYi
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201870043
Subject(s) - electrocatalyst , materials science , catalysis , oxide , cobalt , cobalt oxide , adsorption , graphene , oxygen evolution , oxygen , nanocrystal , surface engineering , metal , chemical engineering , electrolyte , inorganic chemistry , nanotechnology , electrochemistry , electrode , chemistry , organic chemistry , metallurgy , engineering
In article number 1702222 , Yida Deng, Tian‐Yi Ma and co‐workers report active site and atomic configuration engineering on a Co 3 O 4 surface through the controllable synthesis of surface‐tailored Co 3 O 4 nanocrystals anchored on N‐doped graphene. An unusual {112} facets enclosed Co 3 O 4 nanopolyhedron with abundant octahedrally coordinated Co 3+ sites exhibits enhanced oxygen electrocatalytic and Zn‐air performance in alkaline electrolytes owing to the optimized adsorption, activation and desorption behaviors of oxygen‐containing intermediates.

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