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A Tannic Acid–Derived N‐, P‐Codoped Carbon‐Supported Iron‐Based Nanocomposite as an Advanced Trifunctional Electrocatalyst for the Overall Water Splitting Cells and Zinc–Air Batteries
Author(s) -
Qin Qing,
Jang Haeseong,
Li Ping,
Yuan Bing,
Liu Xien,
Cho Jaephil
Publication year - 2019
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201803312
Subject(s) - electrocatalyst , materials science , catalysis , tannic acid , water splitting , oxygen evolution , chemical engineering , nanocomposite , pyrolysis , carbon fibers , electrochemistry , nanoparticle , inorganic chemistry , nanotechnology , chemistry , electrode , composite number , organic chemistry , photocatalysis , composite material , engineering
Rational design and construction of a multifunctional electrocatalyst featuring with high efficiency and low cost is fundamentally important to realize new energy technologies. Herein, a trifunctional electrocatalyst composed of FeP x nanoparticles and Fe–N–C moiety supported on the N‐, P‐codoped carbon (NPC) is masterly synthesized by a facile one‐pot pyrolysis of the mixture of tannic acid, ferrous chloride, and sodium hydrogen phosphate. The synergy of each component in the FeP x /Fe–N–C/NPC catalyst renders high catalytic activities and excellent durability toward both oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER). The electrocatalytic performance and practicability of the robust FeP x /Fe–N–C/NPC catalyst are further investigated under the practical operation conditions. Particularly, the overall water splitting cell assembled by the FeP x /Fe–N–C/NPC catalyst only requires a voltage of 1.58 V to output the benchmark current density of 10 mA cm −2 , which is superior to that of IrO 2 –Pt/C‐based cell. Moreover, the FeP x /Fe–N–C/NPC‐based zinc–air batteries deliver high round‐trip efficiency and remarkable cycling stability, much better than that of Pt/C–IrO 2 pair‐based batteries. This work offers a new strategy to design and synthesize highly effective multifunctional electrocatalysts using cheaper tannic acid derived carbon as support applied in electrochemical energy devices.