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Improved Efficiency and Stability of Pb/Sn Binary Perovskite Solar Cells Fabricated by Galvanic Displacement Reaction
Author(s) -
Zhu Zonglong,
Li Nan,
Zhao Dongbin,
Wang Liduo,
Jen Alex K.Y.
Publication year - 2019
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201802774
Subject(s) - materials science , halide , perovskite (structure) , galvanic cell , metal , thermal stability , relative humidity , single displacement reaction , band gap , chemical engineering , inorganic chemistry , optoelectronics , metallurgy , chemistry , physics , engineering , thermodynamics
Here, a simple and generally applicable method of fabricating efficient and stable Pb‐Sn binary perovskite solar cells (PVSCs) based on a galvanic displacement reaction (GDR) is demonstrated. Different from the commonly used conventional approaches to form perovskite precursor solutions by mixing metal halides and organic halides such as PbI 2 , SnI 2 , MAI, FAI, etc., together, the precursor solutions are formulated by reacting pure Pb‐based perovskite precursor solutions with fine Sn metal powders. After the ratios between Pb and Sn are optimized, high PCEs of 15.85% and 18.21% can be achieved for MAPb 0.4 Sn 0.6 I 3 and (FAPb 0.6 Sn 0.4 I 3 ) 0.85 (MAPb 0.6 Sn 0.4 Br 3 ) 0.15 based PVSCs, which are the highest PCEs among all values reported to date for Pb‐Sn binary PVSCs. Moreover, the GDR perovskite‐based PVSCs exhibit significantly improved ambient and thermal stability with encapsulation, which can retain more than 90% of their initial PCEs after being stored in ambient (relative humidity (RH) ≈50%) for 1000 h or being thermal annealed at 80 °C for more than 120 h in ambient conditions. These results demonstrate the advantage of using GDR to prepare tunable bandgap binary perovskites for devices with greatly improved performance and stability.