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High‐Voltage Li‐Ion Full‐Cells with Ultralong Term Cycle Life at Elevated Temperature
Author(s) -
Qiao Yu,
He Yibo,
Jiang Kezhu,
Liu Yang,
Li Xiang,
Jia Min,
Guo Shaohua,
Zhou Haoshen
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201802322
Subject(s) - electrolyte , materials science , anode , separator (oil production) , cathode , electrochemistry , intercalation (chemistry) , ionic liquid , chemical engineering , lithium (medication) , graphite , high voltage , thermal stability , voltage , inorganic chemistry , electrode , electrical engineering , chemistry , organic chemistry , catalysis , composite material , medicine , physics , endocrinology , thermodynamics , engineering
In order to meet the ever‐growing demand for energy and power densities in rechargeable lithium‐ion batteries for electric vehicles, intensive research efforts are focusing on increasing output voltage and maintaining high capacity. However, the trade‐off for higher voltage is sacrificing the service life of the batteries, since the detrimentally oxidative degradation on the high‐potential cathode side would inevitably poison the whole cell. Thus, optimizing strategies for full‐cells must take into account, cathode/anode‐electrolyte compatibilities, electrochemical reversibility, and even thermal stability for practical applications, which spurs a hierarchical design for full‐cell architecture. Benefitting from its superior oxidative stability, ionic liquid (Li/Pyr 13 TFSI) is employed as catholyte, and equimolar LiTFSI/G 3 complex is used as anolyte due to its high graphite‐intercalation‐chemistry reversibility. Segregated by a metal–organic‐framework‐based separator, advantages and drawbacks of each electrolyte systems can be synergistically tuned within their isolated environments. Encouragingly, assembled by this hybrid‐electrolytes strategy, a LiNi 0.5 Mn 1.5 O 4 (5 V‐class)/graphite Li‐ion full‐cell holds an ultrahigh capacity retention rate of 83.8% over 1000 cycles at harsh elevated temperature.