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Selective Electrochemical H 2 O 2 Production through Two‐Electron Oxygen Electrochemistry
Author(s) -
Jiang Yuanyuan,
Ni Pengjuan,
Chen Chuanxia,
Lu Yizhong,
Yang Ping,
Kong Biao,
Fisher Adrian,
Wang Xin
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201801909
Subject(s) - electrochemistry , catalysis , oxygen evolution , materials science , oxygen , hydrogen peroxide , electrocatalyst , redox , chemical engineering , nanotechnology , inorganic chemistry , electrode , chemistry , organic chemistry , metallurgy , engineering
Direct electrochemical production of hydrogen peroxide (H 2 O 2 ) through two‐electron oxygen electrochemistry, for example, the oxygen reduction in fuel cells or water oxidation in water electrolyzers, could provide an attractive alternative to locally produce this chemical on demand. The efficiency of these processes depends greatly on the availability of cost‐effective catalysts with high selectivity, activity, and stability. In recent years, various novel nanostructured materials have been reported to selectively produce H 2 O 2 . Through combined experimental and theoretical approaches, underlying mechanisms in the electrochemical synthesis of H 2 O 2 via oxygen electrochemistry have been unveiled. Considering the remarkable progress in this area, the authors summarize recent developments regarding the direct production of H 2 O 2 through two‐electron electrochemical oxygen reactions. The fundamental aspects of electrochemical oxygen reactions are first introduced. Various types of catalysts that can effectively produce H 2 O 2 via two‐electron oxygen electrochemistry are then presented. In parallel, the unique structure‐, component‐, and composition‐dependent electrochemical performance together with the underlying catalytic mechanisms are discussed. Finally, a brief conclusion about the recent progress achieved in electrochemical generation of H 2 O 2 and an outlook on future research challenges are given.