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The Renaissance of Luminescent Solar Concentrators: The Role of Inorganic Nanomaterials
Author(s) -
Mazzaro Raffaello,
Vomiero Alberto
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201801903
Subject(s) - materials science , luminescence , nanomaterials , nanotechnology , the renaissance , photovoltaics , optoelectronics , building integrated photovoltaics , photoluminescence , fluorophore , photovoltaic system , optics , fluorescence , physics , electrical engineering , art , art history , engineering
Abstract While luminescent solar concentrators (LSCs) have a simple architecture—a transparent matrix embedding a luminescent fluorophore coupled with solar cells at the lateral side of the LSC slab—multiple paths for possible light losses exist. These are inherently interconnected, and in the past, limited the interest in this device, due to the gap between the theoretical possibilities and experimental achievements. This gap was a result, primarily, of the optical features of the luminescent dyes, since conventional organic luminophores are affected by limited performance in LSC devices. The rise of a wide portfolio of optically active inorganic nanomaterials in the last decade provides an alternative to organic dyes and has lead to a renaissance in the role of LSCs among the unconventional solar energy conversion devices. This paper reviews the latest results in the development of LSCs based on different classes of nanomaterials, focusing on the specific features and critically analyzing the pros and cons of the proposed structures. Particular attention is devoted to the role of the luminescence properties, e.g., the Stokes shift and the photoluminescence quantum yield, with respect to the performance of the LSC device. Future challenges to the successful employment of these devices for building integrated photovoltaics are also discussed.