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Engineering of Mesoscale Pores in Balancing Mass Loading and Rate Capability of Hematite Films for Electrochemical Capacitors
Author(s) -
Song Yu,
Liu Tianyu,
Li Mingyang,
Yao Bin,
Kou Tianyi,
Feng Dongyang,
Wang Fuxin,
Tong Yexiang,
Liu XiaoXia,
Li Yat
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201801784
Subject(s) - hematite , materials science , mesoporous material , oxide , electrochemistry , chemical engineering , capacitance , capacitor , hydrothermal circulation , nanotechnology , electrode , diffusion , metal , supercapacitor , metallurgy , voltage , chemistry , physics , engineering , biochemistry , quantum mechanics , thermodynamics , catalysis
Design and synthesis of metal oxide‐based pseudocapacitive materials to simultaneously achieve high mass loading (e.g., up to 10 mg cm −2 ) and excellent rate capability for electrochemical capacitors is a long‐lasting challenge. These two characteristics are usually mutually exclusive due to the poor ion diffusion kinetics of most metal oxides. Here, a glucose‐assisted hydrothermal method to prepare thick hematite film (>1 µm) with engineerable mesopore size through controlled variation of glucose concentration is demonstrated. The capability of controlling the size of mesopores offers a unique opportunity to investigate for the first time the interplay between mesopore size and electrochemical performance of hematite films. The hematite film with an average mesopore size of 3 nm at an ultrahigh loading of 10 mg cm −2 exhibits an areal capacitance of 1502 mF cm −2 at 1 mA cm −2 , and retains 871.2 mF cm −2 at 50 mA cm −2 . Such performance, to the best of the authors' knowledge, is at the top of the reported hematite electrodes with comparable or even lower mass loadings. The strategy demonstrated herein may be extended to fabricate diverse types of mesoporous metal oxide architectures with improved ion diffusion kinetics, which is critical for a broad range of devices for energy storage and conversion.