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Fast Diffusion of Multivalent Ions Facilitated by Concerted Interactions in Dual‐Ion Battery Systems
Author(s) -
Li Hongyi,
Okamoto Norihiko L.,
Hatakeyama Takuya,
Kumagai Yu,
Oba Fumiyasu,
Ichitsubo Tetsu
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201801475
Subject(s) - ion , materials science , diffusion , chemical physics , battery (electricity) , electrochemistry , divalent , dual (grammatical number) , electrode , nanotechnology , chemistry , thermodynamics , physics , organic chemistry , art , power (physics) , literature , metallurgy
Sluggish solid‐phase diffusion has been an essential issue in developing intercalation electrode materials using multivalent ions. Compared to monovalent Li ions, the diffusion of multivalent ions is still not well understood. Here, combining first‐principles calculations with electrochemical experiments, it is shown that the diffusion of divalent Mg ions is significantly facilitated in Li–Mg dual‐ion systems, and the activation energy is remarkably reduced by the concerted interactions of the preceding Li ions and following Mg ions. Thus, making dual‐ion systems is a promising way to construct high‐energy‐density, rechargeable batteries with multivalent ions. This work will provide a new perspective on solid‐phase diffusion that is typically a rate‐controlling process in battery systems and fuel cell devices.