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High‐Efficiency (Li x Cu 1− x ) 2 ZnSn(S,Se) 4 Kesterite Solar Cells with Lithium Alloying
Author(s) -
CabasVidani Antonio,
Haass Stefan G.,
Andres Christian,
Caballero Raquel,
Figi Renato,
Schreiner Claudia,
Márquez José A.,
Hages Charles,
Unold Thomas,
Bleiner Davide,
Tiwari Ayodhya N.,
Romanyuk Yaroslav E.
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201801191
Subject(s) - kesterite , materials science , band gap , lithium (medication) , analytical chemistry (journal) , chalcogenide , photoluminescence , alloy , alkali metal , microstructure , solid solution , mass fraction , chemical engineering , optoelectronics , metallurgy , composite material , chemistry , czts , medicine , organic chemistry , chromatography , engineering , endocrinology
The performance‐boosting effect of alkali treatments is well known for chalcogenide thin‐film solar cells based on Cu(In,Ga)Se 2 (CIGS) and Cu 2 ZnSn(S,Se) 4 (CZTSSe–kesterite) absorbers. In contrast to heavier alkali elements, lithium is expected to alloy with the kesterite phase leading to the solid solution (Li x Cu 1− x ) 2 ZnSn(S,Se) 4 (LCZTSSe), which offers a way of tuning the semiconductor bandgap by changing the ratio Li/(Li+Cu). Here is presented an experimental series of solution‐processed LCZTSSe with lithium fraction Li/(Li+Cu) ranging from x = 0 to 0.12 in the selenized absorber as measured by means of inductively coupled plasma mass spectrometry. The proportional increase in lattice parameter a and bandgap from 1.05 to 1.18 eV confirms the lithium alloying in the kesterite phase. Increase in grain size is observed for x up to 0.07, whereas a higher lithium fraction leads to a porous absorber morphology due to an inhomogeneous distribution of Li‐containing compounds in the kesterite layer. An increase of the photoluminescence quantum yield is observed as the Li fraction increases in the absorber layer. A champion device exhibits a remarkable efficiency of 11.6% (12.2% active area) for x = 0.06, close to the world record value of 12.6% demonstrating the effectiveness of lithium alloying.