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Fabrication of Hierarchical Potassium Titanium Phosphate Spheroids: A Host Material for Sodium‐Ion and Potassium‐Ion Storage
Author(s) -
Wei Zhixuan,
Wang Dongxue,
Li Malin,
Gao Yu,
Wang Chunzhong,
Chen Gang,
Du Fei
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201801102
Subject(s) - anode , materials science , electrolyte , potassium , electrochemistry , sodium , ion , energy storage , chemical engineering , fabrication , electrode , nanotechnology , chemistry , metallurgy , medicine , alternative medicine , organic chemistry , pathology , power (physics) , physics , quantum mechanics , engineering
Identifying suitable electrode materials for sodium‐ion and potassium‐ion storage holds the key to the development of earth‐abundant energy‐storage technologies. This study reports an anode material based on self‐assembled hierarchical spheroid‐like KTi 2 (PO 4 ) 3 @C nanocomposites synthesized via an electrospray method. Such an architecture synergistically combines the advantages of the conductive carbon network and allows sufficient space for the infiltration of the electrolyte from the porous structure, leading to an impressive electrochemical performance, as reflected by the high reversible capacity (283.7 mA h g −1 for Na‐ion batteries; 292.7 mA h g −1 for K‐ion batteries) and superior rate capability (136.1 mA h g −1 at 10 A g −1 for Na‐ion batteries; 133.1 mA h g −1 at 1 A g −1 for K‐ion batteries) of the resulting material. Moreover, the different ion diffusion behaviors in the two systems are revealed to account for the difference in rate performance. These findings suggest that KTi 2 (PO 4 ) 3 @C is a promising candidate as an anode material for sodium‐ion and potassium‐ion batteries. In particular, the present synthetic approach could be extended to other functional electrode materials for energy‐storage materials.