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In Situ Grown Bimetallic MOF‐Based Composite as Highly Efficient Bifunctional Electrocatalyst for Overall Water Splitting with Ultrastability at High Current Densities
Author(s) -
Senthil Raja Duraisamy,
Chuah XuiFang,
Lu ShihYuan
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201801065
Subject(s) - bifunctional , bimetallic strip , electrocatalyst , materials science , water splitting , anode , catalysis , cathode , nickel , chemical engineering , oxygen evolution , composite number , inorganic chemistry , metal , electrode , electrochemistry , chemistry , metallurgy , composite material , photocatalysis , engineering , biochemistry
A newly designed water‐stable NH 2 ‐MIL‐88B(Fe 2 Ni)‐metal–organic framework (MOF), in situ grown on the surface of a highly conducting 3D macroporous nickel foam (NF), termed NFN‐MOF/NF, is demonstrated to be a highly efficient bifunctional electrocatalyst for overall water splitting with ultrastability at high current densities. The NFN‐MOF/NF achieves ultralow overpotentials of 240 and 87 mV at current density of 10 mA cm −2 for the oxygen evolution reaction and hydrogen evolution reaction, respectively, in 1 m KOH. For the overall water splitting, it requires only an ultralow cell voltage of 1.56 V to reach the current density of 10 mA cm −2 , outperforming the pairing of Pt/C on NF as the cathode and IrO 2 on NF as the anode at the same catalyst loading. The stability of the NFN‐MOF/NF catalyst is also outstanding, exhibiting only a minor chronopotentiometric decay of 7.8% at 500 mA cm −2 after 30 h. The success of the present NFN‐MOF/NF catalyst is attributed to the abundant active centers, the bimetallic clusters {Fe 2 Ni(µ 3 ‐O)(COO) 6 (H 2 O) 3 }, in the MOF, the positive coupling effect between Ni and Fe metal ions in the MOF, and synergistic effect between the MOF and NF.