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A Facile Strategy to Construct Amorphous Spinel‐Based Electrocatalysts with Massive Oxygen Vacancies Using Ionic Liquid Dopant
Author(s) -
Sun Jing,
Guo Niankun,
Shao Zhiyu,
Huang Keke,
Li Yaowen,
He Feng,
Wang Qin
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201800980
Subject(s) - overpotential , dopant , nanoclusters , materials science , oxygen evolution , amorphous solid , heteroatom , spinel , ionic liquid , catalysis , ionic bonding , chemical engineering , oxygen , inorganic chemistry , chemical physics , doping , nanotechnology , chemistry , electrochemistry , crystallography , ion , metallurgy , electrode , organic chemistry , optoelectronics , ring (chemistry) , engineering
Oxygen vacancies are demonstrated to be beneficial to various electrocatalytic reactions. However, integrating oxygen vacancies into an amorphous catalyst with a large specific surface area, and investigating its effect on the oxygen evolution reaction remains a great challenge. Herein, oxygen vacancies are introduced into an amorphous N, P, and F tri‐doped CoFe 2 O 4 using ionic liquid as a dopant. Simultaneously, ultrafine MoS 2 nanoclusters are anchored onto its surface to increase the specific surface area. The vacancy‐rich MoS 2 /NPF‐CoFe 2 O 4 exhibits an overpotential of 250 mV and a small Tafel slope of 41 mV dec −1 , which is the best spinel‐based oxygen evolution reaction (OER) electrocatalysts so far. The excellent performance is attributed to massive oxygen vacancies, amorphous structure, large surface area, and synergistic coupling effects among active species. Density‐functional theory calculations reveal that the electronic structure of the catalyst can be modulated in the presence of heteroatoms and MoS 2 nanoclusters, and then the energy barriers of intermediates are decreased as well, which enhances the OER performance. This design not only provides a simple strategy to construct amorphous structures with abundant oxygen vacancies using ionic liquid‐dopants, but also presents an in‐depth insight into the OER mechanism in alkaline solution.