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Exceptionally High Performance Anode Material Based on Lattice Structure Decorated Double Perovskite Sr 2 FeMo 2/3 Mg 1/3 O 6− δ for Solid Oxide Fuel Cells
Author(s) -
Du Zhihong,
Zhao Hailei,
Li Shanming,
Zhang Yang,
Chang Xiwang,
Xia Qing,
Chen Ning,
Gu Lin,
Świerczek Konrad,
Li Yan,
Yang Tianrang,
An Ke
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201800062
Subject(s) - materials science , crystal structure , anode , perovskite (structure) , cathode , oxide , electrochemistry , crystallography , lattice constant , thermal expansion , diffraction , chemistry , electrode , metallurgy , physics , optics
A novel double perovskite Sr 2 FeMo 2/3 Mg 1/3 O 6− δ is prepared and characterized as an anode material for solid oxide fuel cells (SOFCs). X‐ray diffraction refinement reveals that Mg and Mo cations locate separately in two different B sites (B and B′ in A 2 BB′O 6 ) while Fe occupies both B and B′ sites, forming the lattice structure with the form of Sr 2 (Mg 1/3 Fe 2/3 )(Mo 2/3 Fe 1/3 )O 6− δ . The inactive element Mg doping not only endows the material with excellent redox structural stability but also triggers the creation of antisite defects in the crystal lattice, which provide the material with excellent electrochemical activity. The anode performance of Sr 2 FeMo 2/3 Mg 1/3 O 6− δ is characterized in an La 0.8 Sr 0.2 Ga 0.8 Mg 0.2 O 3− δ electrolyte supported cell with La 0.58 Sr 0.4 Fe 0.8 Co 0.2 O 3− δ cathode. A peak power density of 531, 803, 1038, and 1316 mW cm −2 at 750, 800, 850, and 900 °C, respectively, is achieved in humidified H 2 . The Sr 2 FeMo 2/3 Mg 1/3 O 6− δ shows suitable thermal expansion coefficient (16.9(2) × 10 −6 K −1 ), high electrical conductivity, and good tolerance to carbon deposition and sulfur poisoning. First‐principle computations demonstrate that the presence of Fe B OFe B′ bonds can promote the easy formation and fast migration of oxygen vacancies in the lattice, which are the key to affecting the anode reaction kinetics. The excellent overall performance of Sr 2 FeMo 2/3 Mg 1/3 O 6− δ compound makes it a promising anode material for SOFCs.