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Eco‐Friendly Higher Manganese Silicide Thermoelectric Materials: Progress and Future Challenges
Author(s) -
Liu WeiDi,
Chen ZhiGang,
Zou Jin
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201800056
Subject(s) - materials science , manganese , thermoelectric effect , thermoelectric materials , silicide , environmentally friendly , commercialization , engineering physics , nanotechnology , thermal conductivity , optoelectronics , metallurgy , silicon , composite material , business , ecology , physics , marketing , biology , engineering , thermodynamics
As a promising thermoelectric material, higher manganese silicides are composed of earth‐abundant and eco‐friendly elements, and have attracted extensive attention for future commercialization. In this review, the authors first summarize the crystal structure, band structure, synthesis method, and pristine thermoelectric performance of different higher manganese silicides. After that, the strategies for enhancing electrical performance and reducing lattice thermal conductivity of higher manganese silicides as well as their synergism are highlighted. The application potentials including the chemical and mechanical stability of higher manganese silicides and their energy conversion efficiency of the assembled thermoelectric modules are also summarized. By analyzing the current advances in higher manganese silicides, this review proposes that potential methods of further enhancing zT of higher manganese silicides, lie in enhancing electrical performance while simultaneously reducing lattice thermal conductivity via reducing effective mass, optimizing carrier concentration, and nanostructure engineering.