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A Robust Approach for Efficient Sodium Storage of GeS 2 Hybrid Anode by Electrochemically Driven Amorphization
Author(s) -
Kim JooHyung,
Yun Jong Hyuk,
Kim Do Kyung
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201703499
Subject(s) - anode , materials science , graphene , energy storage , oxide , nanotechnology , annealing (glass) , lithium (medication) , chemical engineering , nanocomposite , electrode , sodium , ion , electrochemistry , metallurgy , medicine , power (physics) , chemistry , physics , quantum mechanics , endocrinology , engineering
Sodium ion batteries (NIBs) have become attractive promising alternatives to lithium ion batteries in a broad field of future energy storage applications. The development of high‐performance anode materials has become an essential factor and a great challenge toward satisfying the requirements for NIBs, advancement. This work is the first report on GeS 2 nanocomposites uniformly distributed on reduced graphene oxide (rGO) as promising anode materials for NIBs prepared via a facile hydrothermal synthesis and a unique carbo‐thermal annealing. The results show that the GeS 2 /rGO hybrid anode yields a high reversible specific capacity of 805 mA h g −1 beyond the theoretical capacity, an excellent rate capability of 616 mA h g −1 at 5 A g −1 , and a cycle retention of 89.4% after 100 cycles. A combined ex situ characterization study reveals that the electrochemically driven amorphization plays a key role in achieving efficient sodium storage by accommodating excess sodium ions in the electrode materials. Understanding the sequential conversion‐alloying reaction mechanism for GeS 2 /rGO hybrid anodes provides a new approach for developing high‐performance energy storage applications.