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Observation of Pseudocapacitive Effect and Fast Ion Diffusion in Bimetallic Sulfides as an Advanced Sodium‐Ion Battery Anode
Author(s) -
Fang Guozhao,
Wu Zhuoxi,
Zhou Jiang,
Zhu Chuyu,
Cao Xinxin,
Lin Tianquan,
Chen Yuming,
Wang Chao,
Pan Anqiang,
Liang Shuquan
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201703155
Subject(s) - materials science , sulfidation , anode , bimetallic strip , sodium ion battery , chemical engineering , diffusion , calcination , sodium , sulfide , battery (electricity) , energy storage , nanocrystal , electrode , ion , nanotechnology , metal , catalysis , faraday efficiency , metallurgy , sulfur , chemistry , physics , biochemistry , power (physics) , quantum mechanics , thermodynamics , engineering
Sodium‐ion batteries (SIBs) are promising next‐generation alternatives due to the low cost and abundance of sodium sources. Yet developmental electrodes in SIBs such as transition metal sulfides have huge volume expansion, sluggish Na + diffusion kinetics, and poor electrical conductivity. Here bimetallic sulfide (Co 9 S 8 /ZnS) nanocrystals embedded in hollow nitrogen‐doped carbon nanosheets are demonstrated with a high sodium diffusion coefficient, pseudocapacitive effect, and excellent reversibility. Such a unique composite structure is designed and synthesized via a facile sulfidation of the CoZn‐MOFs followed by calcination and is highly dependant on the reaction time and temperature. The optimized Co 1 Zn 1 ‐S(600) electrode exhibits excellent sodium storage performance, including a high capacity of 542 mA h g −1 at 0.1 A g −1 , good rate capability at 10 A g −1 , and excellent cyclic stability up to 500 cycles for half‐cell. It also shows potential in full‐cell configuration. Such capabilities will accelerate the adoption of sodium‐ion batteries for electrical energy applications.