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A Chemical Approach to Raise Cell Voltage and Suppress Phase Transition in O3 Sodium Layered Oxide Electrodes
Author(s) -
Sathiya Mariyappan,
Jacquet Quentin,
Doublet MarieLiesse,
Karakulina Olesia M.,
Hadermann Joke,
Tarascon JeanMarie
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201702599
Subject(s) - materials science , electrochemistry , oxide , phase transition , transition metal , phase (matter) , ion , electrode , voltage , sodium , redox , metal , chemical engineering , nanotechnology , inorganic chemistry , chemistry , catalysis , electrical engineering , thermodynamics , metallurgy , organic chemistry , physics , engineering
Sodium ion batteries (NIBs) are one of the versatile technologies for low‐cost rechargeable batteries. O3‐type layered sodium transition metal oxides (NaMO 2 , M = transition metal ions) are one of the most promising positive electrode materials considering their capacity. However, the use of O3 phases is limited due to their low redox voltage and associated multiple phase transitions which are detrimental for long cycling. Herein, a simple strategy is proposed to successfully combat these issues. It consists of the introduction of a larger, nontransition metal ion Sn 4+ in NaMO 2 to prepare a series of NaNi 0.5 Mn 0.5− y Sn y O 2 ( y = 0–0.5) compositions with attractive electrochemical performances, namely for y = 0.5, which shows a single‐phase transition from O3 ⇔ P3 at the very end of the oxidation process. Na‐ion NaNi 0.5 Sn 0.5 O 2 /C coin cells are shown to deliver an average cell voltage of 3.1 V with an excellent capacity retention as compared to an average stepwise voltage of ≈2.8 V and limited capacity retention for the pure NaNi 0.5 Mn 0.5 O 2 phase . This study potentially shows the way to manipulate the O3 NaMO 2 for facilitating their practical use in NIBs.