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Designing Safe Electrolyte Systems for a High‐Stability Lithium–Sulfur Battery
Author(s) -
Chen Wei,
Lei Tianyu,
Wu Chunyang,
Deng Min,
Gong Chuanhui,
Hu Kai,
Ma Yinchang,
Dai Liping,
Lv Weiqiang,
He Weidong,
Liu Xuejun,
Xiong Jie,
Yan Chenglin
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201702348
Subject(s) - electrolyte , anode , materials science , cathode , battery (electricity) , flammable liquid , fast ion conductor , lithium (medication) , electrochemistry , lithium–sulfur battery , inorganic chemistry , chemical engineering , electrode , chemistry , electrical engineering , organic chemistry , engineering , medicine , power (physics) , physics , endocrinology , quantum mechanics
Safety, nontoxicity, and durability directly determine the applicability of the essential characteristics of the lithium (Li)‐ion battery. Particularly, for the lithium–sulfur battery, due to the low ignition temperature of sulfur, metal lithium as the anode material, and the use of flammable organic electrolytes, addressing security problems is of increased difficulty. In the past few years, two basic electrolyte systems are studied extensively to solve the notorious safety issues. One system is the conventional organic liquid electrolyte, and the other is the inorganic solid‐state or quasi‐solid‐state composite electrolyte. Here, the recent development of engineered liquid electrolytes and design considerations for solid electrolytes in tackling these safety issues are reviewed to ensure the safety of electrolyte systems between sulfur cathode materials and the lithium‐metal anode. Specifically, strategies for designing and modifying liquid electrolytes including introducing gas evolution, flame, aqueous, and dendrite‐free electrolytes are proposed. Moreover, the considerations involving a high‐performance Li + conductor, air‐stable Li + conductors, and stable interface performance between the sulfur cathode and the lithium anode for developing all‐solid‐state electrolytes are discussed. In the end, an outlook for future directions to offer reliable electrolyte systems is presented for the development of commercially viable lithium–sulfur batteries.