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Rational Design of Nickel Hydroxide‐Based Nanocrystals on Graphene for Ultrafast Energy Storage
Author(s) -
Zhao Bote,
Zhang Lei,
Zhang Qiaobao,
Chen Dongchang,
Cheng Yong,
Deng Xiang,
Chen Yu,
Murphy Ryan,
Xiong Xunhui,
Song Bo,
Wong ChingPing,
Wang MingSheng,
Liu Meilin
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201702247
Subject(s) - materials science , graphene , electrode , energy storage , rational design , hydroxide , anode , oxide , density functional theory , nanotechnology , nickel , power density , current density , layered double hydroxides , chemical engineering , power (physics) , metallurgy , chemistry , physics , computational chemistry , quantum mechanics , engineering
Compact, light, and powerful energy storage devices are urgently needed for many emerging applications; however, the development of advanced power sources relies heavily on advances in materials innovation. Here, the findings in rational design, one‐pot synthesis, and characterization of a series of Ni hydroxide‐based electrode materials in alkaline media for fast energy storage are reported. Under the guidance of density functional theory calculations and experimental investigations, a composite electrode composed of Co‐/Mn‐substituted Ni hydroxides grown on reduced graphene oxide (rGO) is designed and prepared, demonstrating capacities of 665 and 427 C g −1 at current densities of 2 and 20 A g −1 , respectively. The superior performance is attributed mainly to the low deprotonation energy and the facile electron transport, as elaborated by theoretical calculations. When coupled with an electrode based on organic molecular‐modified rGO, the resulting hybrid device demonstrates an energy density of 74.7 W h kg −1 at a power density of 1.68 kW kg −1 while maintaining capacity retention of 91% after 10,000 cycles (20 A g −1 ). The findings not only provide a promising electrode material for high‐performance hybrid capacitors but also open a new avenue toward knowledge‐based design of efficient electrode materials for other energy storage applications.