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High‐Efficiency Low‐Temperature ZnO Based Perovskite Solar Cells Based on Highly Polar, Nonwetting Self‐Assembled Molecular Layers
Author(s) -
Azmi Randi,
Hadmojo Wisnu Tantyo,
Sinaga Septy,
Lee ChangLyoul,
Yoon Sung Cheol,
Jung In Hwan,
Jang SungYeon
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201701683
Subject(s) - materials science , perovskite (structure) , energy conversion efficiency , wetting , dipole , monolayer , optoelectronics , fabrication , deposition (geology) , active layer , photovoltaic system , self assembled monolayer , nanotechnology , layer (electronics) , chemical engineering , composite material , chemistry , organic chemistry , medicine , paleontology , alternative medicine , pathology , sediment , engineering , biology , ecology , thin film transistor
Abstract Herein, this study reports high‐efficiency, low‐temperature ZnO based planar perovskite solar cells (PSCs) with state‐of‐the‐art performance. They are achieved via a strategy that combines dual‐functional self‐assembled monolayer (SAM) modification of ZnO electron accepting layers (EALs) with sequential deposition of perovskite active layers. The SAMs, constructed from newly synthesized molecules with high dipole moments, act both as excellent surface wetting control layers and as electric dipole layers for ZnO‐EALs. The insertion of SAMs improves the quality of PbI 2 layers and final perovskite layers during sequential deposition, while charge extraction is enhanced via electric dipole effects. Leveraged by SAM modification, our low‐temperature ZnO based PSCs achieve an unprecedentedly high power conversion efficiency of 18.82% with a V OC of 1.13 V, a J SC of 21.72 mA cm −2 , and a FF of 0.76. The strategy used in this study can be further developed to produce additional performance enhancements or fabrication temperature reductions.