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From Surface ZrO 2 Coating to Bulk Zr Doping by High Temperature Annealing of Nickel‐Rich Lithiated Oxides and Their Enhanced Electrochemical Performance in Lithium Ion Batteries
Author(s) -
Schipper Florian,
Bouzaglo Hana,
Dixit Mudit,
Erickson Evan M.,
Weigel Tina,
Talianker Michael,
Grinblat Judith,
Burstein Larisa,
Schmidt Michael,
Lampert Jordan,
Erk Christoph,
Markovsky Boris,
Major Dan Thomas,
Aurbach Doron
Publication year - 2018
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201701682
Subject(s) - materials science , annealing (glass) , doping , electrochemistry , zirconium , chemical engineering , coating , nickel , cathode , inert , surface modification , lithium (medication) , metallurgy , composite material , electrode , chemistry , engineering , medicine , optoelectronics , endocrinology , physics , quantum mechanics
One of the major hurdles of Ni‐rich cathode materials Li 1+ x (Ni x Co z Mn z ) w O 2 , y > 0.5 for lithium‐ion batteries is their low cycling stability especially for compositions with Ni ≥ 60%, which suffer from severe capacity fading and impedance increase during cycling at elevated temperatures (e.g., 45 °C). Two promising surface and structural modifications of these materials to alleviate the above drawback are (1) coatings by electrochemically inert inorganic compounds (e.g., ZrO 2 ) or (2) lattice doping by cations like Zr 4+ , Al 3+ , Mg 2+ , etc. This paper demonstrates the enhanced electrochemical behavior of Ni‐rich material LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811) coated with a thin ZrO 2 layer. The coating is produced by an easy and scalable wet chemical approach followed by annealing the material at ≥700 °C under oxygen that results in Zr doping. It is established that some ZrO 2 remains even after annealing at ≥800 °C as a surface layer on NCM811. The main finding of this work is the enhanced cycling stability and lower impedance of the coated/doped NCM811 that can be attributed to a synergetic effect of the ZrO 2 coating in combination with a zirconium doping.