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Highly Efficient and Durable Pd Hydride Nanocubes Embedded in 2D Amorphous NiB Nanosheets for Oxygen Reduction Reaction
Author(s) -
Lu Yizhong,
Wang Jiong,
Peng Yuecheng,
Fisher Adrian,
Wang Xin
Publication year - 2017
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201700919
Subject(s) - materials science , electrocatalyst , hydride , amorphous solid , electrochemistry , catalysis , chemical engineering , thermal stability , inorganic chemistry , electrode , metal , organic chemistry , chemistry , metallurgy , engineering
A highly efficient and durable electrocatalyst of Pd hydride nanocubes encapsulated within 2D amorphous Ni‐B nanosheets is reported. The PdH 0.43 nanocubes are first synthesized via a simple N , N ‐dimethylformamide thermal treatment. The as‐synthesized PdH 0.43 nanocubes are then encapsulated in 2D amorphous NiB nanosheets by NaBH 4 reduction in the presence of nickel species. During the NaBH 4 treatment, the PdH 0.43 can be further transformed into PdH 0.706 due to the presence of endogenous H 2 . Electrochemical studies demonstrate that the degree of hydride of Pd nanocubes (PdH x ) plays an important role in the enhancement of their oxygen reduction reaction (ORR) activity. With increasing x value, both the activity and stability increase significantly. At 0.90 V versus reversible hydrogen electrode, the ORR activity of PdH 0.706 @Ni‐B reaches 1.05 A mg Pd −1 , which is nearly five times higher than that of the state‐of‐the‐art Pt catalysts. Accelerated durability tests show that even after 10 000 potential cycles, there is negligible shift in their half‐wave potential and no shape and structure change occurs, indicating the incorporation of amorphous 2D Ni‐B nanosheets can greatly improve their stability without compromising their activity. The present study illustrates the importance of high degree of hydride and presence of amorphous Ni‐B nanosheets on the enhancement of ORR activity for Pd‐based electrocatalyst.