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Retracted: Earth‐Abundant Iron Diboride (FeB 2 ) Nanoparticles as Highly Active Bifunctional Electrocatalysts for Overall Water Splitting
Author(s) -
Li Hui,
Wen Peng,
Li Qi,
Dun Chaochao,
Xing Junheng,
Lu Chang,
Adhikari Shiba,
Jiang Lin,
Carroll David L.,
Geyer Scott M.
Publication year - 2017
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201700513
Subject(s) - water splitting , oxygen evolution , materials science , electrocatalyst , overpotential , tafel equation , bifunctional , inorganic chemistry , faraday efficiency , electrolysis , electrolyte , chemical engineering , electrolysis of water , alkaline water electrolysis , reversible hydrogen electrode , catalysis , electrode , electrochemistry , chemistry , working electrode , biochemistry , photocatalysis , engineering
Developing efficient, durable, and earth‐abundant electrocatalysts for both hydrogen and oxygen evolution reactions is important for realizing large‐scale water splitting. The authors report that FeB 2 nanoparticles, prepared by a facile chemical reduction of Fe 2+ using LiBH 4 in an organic solvent, are a superb bifunctional electrocatalyst for overall water splitting. The FeB 2 electrode delivers a current density of 10 mA cm −2 at overpotentials of 61 mV for hydrogen evolution reaction (HER) and 296 mV for oxygen evolution reaction (OER) in alkaline electrolyte with Tafel slopes of 87.5 and 52.4 mV dec −1 , respectively. The electrode can sustain the HER at an overpotential of 100 mV for 24 h and OER for 1000 cyclic voltammetry cycles with negligible degradation. Density function theory calculations demonstrate that the boron‐rich surface possesses appropriate binding energy for chemisorption and desorption of hydrogen‐containing intermediates, thus favoring the HER process. The excellent OER activity of FeB 2 is ascribed to the formation of a FeOOH/FeB 2 heterojunction during water oxidation. An alkaline electrolyzer is constructed using two identical FeB 2 ‐NF electrodes as both anode and cathode, which can achieve a current density of 10 mA cm −2 at 1.57 V for overall water splitting with a faradaic efficiency of nearly 100%, rivalling the integrated state‐of‐the‐art Pt/C and RuO 2 /C.