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A Conductive Molecular Framework Derived Li 2 S/N,P‐Codoped Carbon Cathode for Advanced Lithium–Sulfur Batteries
Author(s) -
Zhang Jun,
Shi Ye,
Ding Yu,
Peng Lele,
Zhang Wenkui,
Yu Guihua
Publication year - 2017
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201602876
Subject(s) - faraday efficiency , materials science , cathode , anode , electrochemistry , polyaniline , sulfur , inorganic chemistry , chemical engineering , carbon fibers , lithium–sulfur battery , conductivity , electrode , composite number , composite material , chemistry , metallurgy , polymerization , engineering , polymer
Li 2 S is one of the most promising cathode materials for Li‐ion batteries because of its high theoretical capacity and compatibility with Li‐metal‐free anode materials. However, the poor conductivity and electrochemical reactivity lead to low initial capacity and severe capacity decay. In this communication, a nitrogen and phosphorus codoped carbon (N,P–C) framework derived from phytic acid doped polyaniline hydrogel is designed to support Li 2 S nanoparticles as a binder‐free cathode for Li–S battery. The porous 3D architecture of N and P codoped carbon provides continuous electron pathways and hierarchically porous channels for Li ion transport. Phosphorus doping can also suppress the shuttle effect through strong interaction between sulfur and the carbon framework, resulting in high Coulombic efficiency. Meanwhile, P doping in the carbon framework plays an important role in improving the reaction kinetics, as it may help catalyze the redox reactions of sulfur species to reduce electrochemical polarization, and enhance the ionic conductivity of Li 2 S. As a result, the Li 2 S/N,P–C composite electrode delivers a stable capacity of 700 mA h g −1 with average Coulombic efficiency of 99.4% over 100 cycles at 0.1C and an areal capacity as high as 2 mA h cm −2 at 0.5C.