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Four‐Terminal Perovskite/Silicon Multijunction Solar Modules
Author(s) -
Jaysankar Manoj,
Qiu Weiming,
van Eerden Maarten,
Aernouts Tom,
Gehlhaar Robert,
Debucquoy Maarten,
Paetzold Ulrich W.,
Poortmans Jef
Publication year - 2017
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201602807
Subject(s) - materials science , perovskite (structure) , optoelectronics , crystalline silicon , silicon , energy conversion efficiency , photovoltaic system , solar cell , monocrystalline silicon , triiodide , photovoltaics , solar cell efficiency , electrode , electrical engineering , dye sensitized solar cell , chemical engineering , engineering , chemistry , electrolyte
Multijunction solar cells employing perovskite and crystalline‐silicon (c‐Si) light absorbers bear the exciting potential to surpass the efficiency limit of market‐leading single‐junction c‐Si solar cells. However, scaling up this technology and maintaining high efficiency over large areas are challenging as evidenced by the small‐area perovskite/c‐Si multijunction solar cells reported so far. In this work, a scalable four‐terminal multijunction solar module design employing a 4 cm 2 semitransparent methylammonium lead triiodide perovskite solar module stacked on top of an interdigitated back contact c‐Si solar cell of identical area is demonstrated. With a combination of optimized transparent electrodes and efficient module design, the perovskite/c‐Si multijunction solar modules exhibit power conversion efficiencies of 22.6% on 0.13 cm 2 and 20.2% on 4 cm 2 aperture area. Furthermore, a detailed optoelectronic loss analysis along with strategies to enhance the performance is discussed.

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