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Improved Performance of Ternary Polymer Solar Cells Based on A Nonfullerene Electron Cascade Acceptor
Author(s) -
Fan Baobing,
Zhong Wenkai,
Jiang XiaoFang,
Yin Qingwu,
Ying Lei,
Huang Fei,
Cao Yong
Publication year - 2017
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201602127
Subject(s) - materials science , ternary operation , polymer solar cell , acceptor , short circuit , absorption (acoustics) , band gap , energy conversion efficiency , polymer , open circuit voltage , heterojunction , electron acceptor , cascade , optoelectronics , chromophore , chemical engineering , photochemistry , voltage , composite material , condensed matter physics , chemistry , physics , quantum mechanics , computer science , engineering , programming language
Efficient ternary polymer solar cells are constructed by incorporating an electron‐deficient chromophore (5 Z ,5′ Z )‐5,5′‐((7,7′‐(4,4,9,9‐tetrakis(4‐hexylphenyl)‐4,9‐dihydro‐ s ‐indaceno[1,2‐ b :5,6‐ b ′]dithiophene‐2,7‐diyl) bis (6‐fluorobenzo[ c ][1,2,5]thiadiazole‐7,4‐diyl)) bis (methanylylidene)) bis (3‐ethyl‐2‐thioxothiazolidin‐4‐one) (IFBR) as an additional component into the bulk‐heterojunction film that consists of a wide‐bandgap conjugated benzodithiophene‐ alt ‐difluorobenzo[1,2,3]triazole based copolymer and a fullerene acceptor. With respect to the binary blend films, the incorporation of a certain amount of IFBR leads to simultaneously enhanced absorption coefficient, obviously extended absorption band, and improved open‐circuit voltage. Of particular interest is that devices based on ternary blend film exhibit much higher short‐circuit current densities than the binary counterparts, which can be attributed to the extended absorption profiles, enhanced absorption coefficient, favorable film morphology, as well as formation of cascade energy level alignment that is favorable for charge transfer. Further investigation indicates that the ternary blend device exhibits much shorter charge carrier extraction time, obviously reduced trap density and suppressed trap‐assisted recombination, which is favorable for achieving high short‐circuit current. The combination of these beneficial aspects leads to a significantly improved power conversion efficiency of 8.11% for the ternary device, which is much higher than those obtained from the binary counterparts. These findings demonstrate that IFBR can be a promising electron‐accepting material for the construction of ternary blend films toward high‐performance polymer solar cells.