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NiFe‐Based (Oxy)hydroxide Catalysts for Oxygen Evolution Reaction in Non‐Acidic Electrolytes
Author(s) -
Dionigi Fabio,
Strasser Peter
Publication year - 2016
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201600621
Subject(s) - oxygen evolution , catalysis , electrolyte , materials science , hydroxide , electrocatalyst , electrochemistry , oxygen , stoichiometry , inorganic chemistry , nanomaterials , oxygen reduction reaction , chemical engineering , nanotechnology , chemistry , electrode , organic chemistry , engineering
NiFe‐based (oxy)hydroxides are highly active catalysts for the oxygen evolution reaction in alkaline electrolyte solutions. These catalysts can be synthesized in different ways leading to nanomaterials and thin films with distinct morphologies, stoichiometries and long‐range order. Notably, their structure evolves under oxygen evolution operating conditions with respect to the as‐synthesized state. Therefore, many researchers have dedicated their efforts on the identification of the catalytic active sites employing in operando experimental methods and theoretical calculations. These investigations are pivotal to rationally design materials with outstanding performances that will constitute the anodes of practical commercial alkaline electrolyzers. The family of NiFe‐based oxyhydroxide catalysts reported in recent years is addressed and the actual state of the research with special focus on the understanding of the oxygen‐evolution‐reaction active sites and phase is described. Finally, an overview on the proposed oxygen‐evolution‐reaction mechanisms occurring on NiFe‐based oxyhydroxide electrocatalysts is provided.