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Amorphous Cobalt Boride (Co 2 B) as a Highly Efficient Nonprecious Catalyst for Electrochemical Water Splitting: Oxygen and Hydrogen Evolution
Author(s) -
Masa Justus,
Weide Philipp,
Peeters Daniel,
Sinev Ilya,
Xia Wei,
Sun Zhenyu,
Somsen Christoph,
Muhler Martin,
Schuhmann Wolfgang
Publication year - 2016
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201502313
Subject(s) - oxygen evolution , catalysis , water splitting , cobalt , electrocatalyst , materials science , boride , inorganic chemistry , electrochemistry , amorphous solid , reversible hydrogen electrode , electrolysis of water , chemical engineering , electrolyte , electrolysis , chemistry , electrode , crystallography , working electrode , metallurgy , biochemistry , photocatalysis , engineering
It is demonstrated that amorphous cobalt boride (Co 2 B) prepared by the chemical reduction of CoCl 2 using NaBH 4 is an exceptionally efficient electrocatalyst for the oxygen evolution reaction (OER) in alkaline electrolytes and is simultaneously active for catalyzing the hydrogen evolution reaction (HER). The catalyst achieves a current density of 10 mA cm −2 at 1.61 V on an inert support and at 1.59 V when impregnated with nitrogen‐doped graphene. Stable performance is maintained at 10 mA cm −2 for at least 60 h. The optimized catalyst, Co 2 B annealed at 500 °C (Co 2 B‐500) evolves oxygen more efficiently than RuO 2 and IrO 2 , and its performance matches the best cobalt‐based catalysts reported to date. Co 2 B is irreversibly oxidized at OER conditions to form a CoOOH surface layer. The active form of the catalyst is therefore represented as CoOOH/Co 2 B. EXAFS observations indicate that boron induces lattice strain in the crystal structure of the metal, which potentially diminishes the thermodynamic and kinetic barrier of the hydroxylation reaction, formation of the OOH* intermediate, a key limiting step in the OER.