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Multifunctional Coatings from Scalable Single Source Precursor Chemistry in Tandem Photoelectrochemical Water Splitting
Author(s) -
Lai YiHsuan,
Palm David W.,
Reisner Erwin
Publication year - 2015
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201501668
Subject(s) - water splitting , materials science , bimetallic strip , tandem , bifunctional , photocathode , coating , nanotechnology , noble metal , chemical engineering , semiconductor , catalysis , metal , photocatalysis , optoelectronics , chemistry , metallurgy , composite material , biochemistry , physics , engineering , quantum mechanics , electron
The straightforward and inexpensive fabrication of stabilized and activated photoelectrodes for application to tandem photoelectrochemical (PEC) water splitting is reported. Semiconductors such as Si, WO 3 , and BiVO 4 can be coated with a composite layer formed upon hydrolytic decomposition of heterobimetallic single source precursors (SSPs) based on Ti and Ni, or Ti and Co in a simple single‐step process under ambient conditions. The resulting 3d‐transition metal oxide composite films are multifunctional, as they protect the semiconductor electrode from corrosion with an amorphous TiO 2 coating and act as bifunctional electrocatalysts for H 2 and O 2 evolution based on catalytic Ni or Co species. Thus, this approach enables the use of the same precursors for both photoelectrodes in tandem PEC water splitting, and SSP chemistry is thereby established as a highly versatile low‐cost approach to protect and activate photoelectrodes. In an optimized system, SSP coating of a Si photocathode and a BiVO 4 photoanode resulted in a benchmark noble metal‐free dual‐photoelectrode tandem PEC cell for overall solar water splitting with an applied bias solar‐to‐hydrogen conversion efficiency of 0.59% and a half‐life photostability of 5 h.