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Amino‐Functionalized Conjugated Polymer as an Efficient Electron Transport Layer for High‐Performance Planar‐Heterojunction Perovskite Solar Cells
Author(s) -
Sun Chen,
Wu Zhihong,
Yip HinLap,
Zhang Hua,
Jiang XiaoFang,
Xue Qifan,
Hu Zhicheng,
Hu Zhanhao,
Shen Yan,
Wang Mingkui,
Huang Fei,
Cao Yong
Publication year - 2016
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201501534
Subject(s) - materials science , trihalide , polymer solar cell , perovskite (structure) , energy conversion efficiency , chemical engineering , work function , optoelectronics , hybrid solar cell , dielectric spectroscopy , photoactive layer , kelvin probe force microscope , polymer , layer (electronics) , nanotechnology , organic chemistry , composite material , electrode , chemistry , engineering , halide , electrochemistry , atomic force microscopy
An amino‐functionalized copolymer with a conjugated backbone composed of fluorene, naphthalene diimide, and thiophene spacers (PFN‐2TNDI) is introduced as an alternative electron transport layer (ETL) to replace the commonly used [6,6]‐Phenyl‐C61‐butyric acid methyl ester (PCBM) in the p–i–n planar‐heterojunction organometal trihalide perovskite solar cells. A combination of characterizations including photoluminescence (PL), time‐resolved PL decay, Kelvin probe measurement, and impedance spectroscopy is used to study the interfacial effects induced by the new ETL. It is found that the amines on the polymer side chains not only can passivate the surface traps of perovskite to improve the electron extraction properties, they also can reduce the work function of the metal cathode by forming desired interfacial dipoles. With these dual functionalities, the resulted solar cells outperform those based on PCBM with power conversion efficiency (PCE) increased from 12.9% to 16.7% based on PFN‐2TNDI. In addition to the performance enhancement, it is also found that a wide range of thicknesses of the new ETL can be applied to produce high PCE devices owing to the good electron transport property of the polymer, which offers a better processing window for potential fabrication of perovskite solar cells using large‐area coating method.