Premium
Solar Rechargeable Batteries Based on Lead–Organohalide Electrolyte
Author(s) -
Wang Qiong,
Chen Hongjun,
McFarland Eric,
Wang Lianzhou
Publication year - 2015
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201501418
Subject(s) - electrolyte , materials science , battery (electricity) , solar cell , energy conversion efficiency , electrochemistry , dye sensitized solar cell , energy storage , photovoltaic system , electrochemical cell , energy transformation , chemical engineering , inorganic chemistry , electrode , optoelectronics , chemistry , electrical engineering , power (physics) , physics , quantum mechanics , thermodynamics , engineering
A dye‐sensitized solar cell (DSC) with in situ energy storage capacity is demonstrated using a lead–organohalide electrolyte CH 3 NH 3 I·PbCl 2 (LOC) to replace the conventional I − /I 3 − electrolyte. The coupling of lead and iodine in one electrolyte creates a dual‐function rechargeable solar battery that combines the working processes of photoelectrochemical cells with electrochemical batteries. Optimization of the H + concentration in the electrolyte leads to increased photocharging efficiency and storage. The power conversion efficiency of the LOC–DSC is 8.6% under one sun illumination (AM 1.5, 100 mW cm −2 ) as a DSC. When operating as a battery, Faraday efficiency can be achieved as high as 81.5% using a bromide‐based CH 3 NH 3 Br·PbBr 2 (LOB) electrolyte in a DSC configuration. This new cell design suggests a means of combining photovoltaic energy conversion and electrical energy storage.