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Charge Accumulation and Hysteresis in Perovskite‐Based Solar Cells: An Electro‐Optical Analysis
Author(s) -
Wu Bo,
Fu Kunwu,
Yantara Natalia,
Xing Guichuan,
Sun Shuangyong,
Sum Tze Chien,
Mathews Nripan
Publication year - 2015
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201500829
Subject(s) - materials science , perovskite (structure) , hysteresis , photocurrent , photoluminescence , optoelectronics , solar cell , chemical physics , electroluminescence , ion , photovoltaic system , nanotechnology , condensed matter physics , chemical engineering , chemistry , electrical engineering , physics , organic chemistry , layer (electronics) , engineering
Organic–inorganic hybrid perovskite solar cells based on CH 3 NH 3 PbI 3 have achieved great success with efficiencies exceeding 20%. However, there are increasing concerns over some reported efficiencies as the cells are susceptible to current–voltage ( I–V ) hysteresis effects. It is therefore essential that the origins and mechanisms of the I–V hysteresis can clearly be understood to minimize or eradicate these hysteresis effects completely for reliable quantification. Here, a detailed electro‐optical study is presented that indicates the hysteresis originates from lingering processes persisting from sub‐second to tens of seconds. Photocurrent transients, photoluminescence, electroluminescence, quasi‐steady state photoinduced absorption processes, and X‐ray diffraction in the perovskite solar cell configuration have been monitored. The slow processes originate from the structural response of the CH 3 NH 3 PbI 3 upon E‐field application and/or charge accumulation, possibly involving methylammonium ions rotation/displacement and lattice distortion. The charge accumulation can arise from inefficient charge transfer at the perovskite interfaces, where it plays a pivotal role in the hysteresis. These findings underpin the significance of efficient charge transfer in reducing the hysteresis effects. Further improvements of CH 3 NH 3 PbI 3 ‐based perovskite solar cells are possible through careful surface engineering of existing TiO 2 or through a judicious choice of alternative interfacial layers.