Premium
Efficient, Large Area, and Thick Junction Polymer Solar Cells with Balanced Mobilities and Low Defect Densities
Author(s) -
Armin Ardalan,
Hambsch Mike,
Wolfer Pascal,
Jin Hui,
Li Jun,
Shi Zugui,
Burn Paul L.,
Meredith Paul
Publication year - 2015
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201401221
Subject(s) - materials science , mobilities , polymer , optoelectronics , engineering physics , composite material , social science , sociology , engineering
The high power conversion efficiencies (PCEs) of laboratory‐scale polymer‐based organic solar cells are yet to translate to large area modules because of a number of factors including the relatively large sheet resistance of available transparent conducting electrodes (TCEs), and the high defect densities associated with thin organic semiconductor junctions. The TCE problem limits device architectures to narrow connected strips (<1 cm) causing serious fabrication difficulties and extra costs. Thin junctions are required because of poor charge transport (imbalanced mobilities) in the constituent organic semiconductors. These issues are addressed using a combination of approaches to create thick junctions conformally coated on low sheet resistance metal grid TCEs. An essential feature of these thick junctions is balanced carrier mobilities, which affords high fill factors and efficient carrier extraction. Conformal coating is achieved by promoting enhanced intermolecular interactions in the coating solution using a high molecular weight polymeric semiconductor and appropriate solvent system. This combination of balanced mobilities, conformal coating and metallic grid TCEs is a simple and generic approach to the fabrication of defect‐free large area organic solar cells (OSCs). The approach is demonstrated with 25 cm 2 monolithic devices possessing aperture‐corrected power conversion efficiencies of 5% and fill factors exceeding 0.5.