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High Thermoelectric Efficiency of n‐type PbS
Author(s) -
Wang Heng,
Schechtel Eugen,
Pei Yanzhong,
Snyder G. Jeffrey
Publication year - 2013
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201200683
Subject(s) - materials science , thermoelectric effect , thermoelectric materials , crystallite , doping , effective mass (spring–mass system) , thermal conductivity , nanotechnology , optoelectronics , composite material , metallurgy , thermodynamics , physics , quantum mechanics
Abstract PbS shares several features with the other lead chalcogenides PbX (X: Te, Se), which are good thermoelectric materials. PbS has a potential advantage in that it is quite earth abundant and inexpensive. In this work we tune the transport properties in n‐type, single‐phase polycrystalline PbS 1‐x Cl x (x ≤ 0.008) with different carrier densities. Lead chloride provides a nearly 100% efficient doping control up to 1.2 × 10 20 cm −3 . The maximum zT achieved at 850 K is 0.7 with a predicted zT ∼ 1 at 1000 K. This is about twice as high as what was previously reported (∼0.4) for binary PbS. Compared with the other lead chalcogenides the higher effective mass and higher lattice thermal conductivity makes binary PbS an inferior thermoelectric material. However this study also predicts greater potential of zT improvement in PbS by material engineering such as alloying or nanostructuring compared to PbSe or PbTe. Considering their abundance and low cost, PbS based materials are quite competitive among the lead chalcogenides for thermoelectric applications.