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Polyester Separators for Lithium‐Ion Cells: Improving Thermal Stability and Abuse Tolerance
Author(s) -
Orendorff Christopher J.,
Lambert Timothy N.,
Chavez Carlos A.,
Bencomo Marlene,
Fenton Kyle R.
Publication year - 2013
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201200292
Subject(s) - materials science , polyolefin , separator (oil production) , polyester , thermal runaway , composite material , thermal stability , electrolyte , carbon black , polymer , wetting , chemical engineering , layer (electronics) , battery (electricity) , electrode , power (physics) , chemistry , physics , natural rubber , engineering , thermodynamics , quantum mechanics
This report describes the preparation and performance of electro‐spun polyester‐based separators for lithium‐ion batteries. Polyester fibers (200–500 nm) are electro‐spun into nonwoven mats and pressed into separator sheets ∼55 μm thick. The resulting polyester separators are 75% porous, highly permeable (Gurley number (s/100 mL) = 6), and have good wettability with conventional carbonate‐based electrolyte. In NMC/graphite lithium‐ion cells, results show comparable performance to commercially available polyolefin separators (rate, capacity fade, and reactivity) but with improved thermal stability to >200 °C. The use of this higher melting temperature polymer separator is one approach to close the gap between potential thermal instabilities (softening, shrinking, melting, etc.) of separators and the onset of thermal runaway reactions of commonly used cathode materials.