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Synthesis, Characterization, and Structural Modeling of High‐Capacity, Dual Functioning MnO 2 Electrode/Electrocatalysts for Li‐O 2 Cells
Author(s) -
Trahey Lynn,
Karan Naba K.,
Chan Maria K. Y.,
Lu Jun,
Ren Yang,
Greeley Jeffrey,
Balasubramanian Mahalingam,
Burrell Anthony K.,
Curtiss Larry A.,
Thackeray Michael M.
Publication year - 2013
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201200037
Subject(s) - electrocatalyst , lithium (medication) , electrolyte , materials science , electrochemistry , electrode , inorganic chemistry , lithium oxide , oxide , chemical engineering , chemistry , lithium vanadium phosphate battery , engineering , medicine , metallurgy , endocrinology
It has become clear that cycling lithium‐oxygen cells in carbonate electrolytes is impractical, as electrolyte decomposition, triggered by oxygen reduction products, dominates the cell chemistry. This research shows that employing an α ‐MnO 2 /ramsdellite‐MnO 2 electrode/electrocatalyst results in the formation of lithium‐oxide‐like discharge products in propylene carbonate, which has been reported to be extremely susceptible to decomposition. X‐ray photoelectron data have shown that what are likely lithium oxides (Li 2 O 2 and Li 2 O) appear to form and decompose on the air electrode surface, particularly at the MnO 2 surface, while Li 2 CO 3 is also formed. By contrast, cells without α ‐MnO 2 /ramsdellite‐MnO 2 fail rapidly in electrochemical cycling, likely due to the differences in the discharge product. Relatively high electrode capacities, up to 5000 mAh/g (carbon + electrode/electrocatalyst), have been achieved with non‐optimized air electrodes. Insights into reversible insertion reactions of lithium, lithium peroxide (Li 2 O 2 ) and lithium oxide (Li 2 O) in the tunnels of α ‐MnO 2 , and the reaction of lithium with ramsdellite‐MnO 2 , as determined by first principles density functional theory calculations, are used to provide a possible explanation for some of the observed results. It is speculated that a Li 2 O‐stabilized and partially‐lithiated electrode component, 0.15Li 2 O· α ‐Li x MnO 2 , that has Mn 4+/3+ character may facilitate the Li 2 O 2 /Li 2 O discharge/charge chemistries providing dual electrode/electrocatalyst functionality.