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Minimizing Energy Losses in Dye‐Sensitized Solar Cells Using Coordination Compounds as Alternative Redox Mediators Coupled with Appropriate Organic Dyes
Author(s) -
Stergiopoulos Thomas,
Falaras Polycarpos
Publication year - 2012
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201100781
Subject(s) - triiodide , redox , iodide , dye sensitized solar cell , ferrocene , materials science , photovoltaic system , solar cell , organic solar cell , photochemistry , combinatorial chemistry , chemical engineering , nanotechnology , inorganic chemistry , chemistry , electrochemistry , optoelectronics , electrode , electrical engineering , electrolyte , metallurgy , engineering
To further boost the efficiency of dye‐sensitized solar cells, a correct evaluation of the real limitations of this type of solar cell should be conducted. From a simple analysis of the photovoltaic data found in the literature, it is evident that the V oc decrease, through energy losses, seems to be the most crucial factor diminishing the overall system efficiency. In particular, losses arising from the regeneration of the dye by the iodide/triiodide redox mediator are huge. The most convenient manner to recuperate these losses is the use of alternative redox mediators with more positive redox potentials than that of the iodide‐based shuttle. Among various types of redox active compounds, ferrocene/ferrocenium, Cu +/2+ , and Co 2+/3+ complexes are found to be the most effective in solar cells and the obtained efficiencies of more than 12% clearly show that a breakthrough is close, paving revolutionary roads towards making new records.