Premium
Nanowire‐Based Three‐Dimensional Transparent Conducting Oxide Electrodes for Extremely Fast Charge Collection
Author(s) -
Noh Jun Hong,
Han Hyun Soo,
Lee Sangwook,
Kim Jin Young,
Hong Kug Sun,
Han GilSang,
Shin Hyunjung,
Jung Hyun Suk
Publication year - 2011
Publication title -
advanced energy materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 10.08
H-Index - 220
eISSN - 1614-6840
pISSN - 1614-6832
DOI - 10.1002/aenm.201100241
Subject(s) - materials science , nanowire , dye sensitized solar cell , mesoporous material , optoelectronics , anatase , indium tin oxide , nanotechnology , electrode , solar cell , oxide , indium , layer (electronics) , electrolyte , photocatalysis , chemistry , metallurgy , catalysis , biochemistry
A 3D transparent conducting oxide (3D‐TCO) has been fabricated by growing Sn‐doped indium oxide (ITO) nanowire arrays on glass substrates via a vapor transport method. The 3D TCO charge‐collection properties have been compared to those of conventional two‐dimensional TCO (2D‐TCO) thin films. For use as a photoelectrode in dye‐sensitized solar cells, ITO‐TiO 2 core‐shell nanowire arrays were prepared by depositing a 45 nm‐thick mesoporous TiO 2 shell layer consisting of ∼6 nm anatase nanoparticles using TiCl 4 treatments. Dye‐sensitized solar cells fabricated using these ITO‐TiO 2 core‐shell nanowire arrays show extremely fast charge collection owing to the shorter electron paths across the 45 nm‐thick TiO 2 shell compared to the 2D TCO. Interestingly, the charge‐collection time does not increase with the overall electrode thickness, which is counterintuitive to conventional diffusion models. This result implies that, in principle, maximum light harvesting can be achieved without hindering the charge collection. The proposed new 3D TCO should also be attractive for other photovoltaic applications where the active layer thickness is limited by poor charge collection.