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Simultaneously Improved Thermoelectric and Mechanical Properties Driven by MgB 2 Doping in Bi 0.4 Sb 1.6 Te 3 Based Alloys
Author(s) -
Qin Haixu,
Cui Bo,
Wang Wei,
Sun Sibo,
Qin Dandan,
Guo Muchun,
Xie Liangjun,
Guo Fengkai,
Cai Wei,
Sui Jiehe
Publication year - 2021
Publication title -
advanced electronic materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.25
H-Index - 56
ISSN - 2199-160X
DOI - 10.1002/aelm.202100173
Subject(s) - materials science , thermoelectric effect , thermoelectric materials , bismuth , machinability , doping , fabrication , alloy , metallurgy , antimony , grain boundary , engineering physics , optoelectronics , microstructure , nanotechnology , composite material , thermodynamics , thermal conductivity , medicine , physics , alternative medicine , pathology , engineering , machining
Bi 2 Te 3 ‐based alloys are the most mature and widely used thermoelectric materials since their z T value has been significantly improved in past decades. However, the poor mechanical strength and machinability derived from the easy cleavage along basal planes not only produce many scraps in the device fabrication process but also lead the devices unstable in the actual service. In this work, a tiny amount of MgB 2 is induced in the Bi 0.4 Sb 1.6 Te 3 alloy to simultaneously enhance the thermoelectric and mechanical properties. In detail, magnesium atoms occupy the bismuth/antimony sites to optimize the carrier concentration and suppress the bipolar effect, pushing the average z T value up to 1.16 ranging from 300 to 500 K, which catches up with the current highest level in p ‐type Bi 2 Te 3 ‐based materials. Moreover, the precipitation phase, boron nanoparticles, distributed at the grain boundaries can effectively improve the compressive strength from 166 to 239 MPa. The prominent thermoelectric and mechanical properties endow the materials with great potential for commercial applications.