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Mechanistic Understanding of the Interactions and Pseudocapacitance of Multi‐Electron Redox Organic Molecules Sandwiched between MXene Layers
Author(s) -
Boota Muhammad,
Hussain Tanveer,
Yang Long,
Bécuwe Matthieu,
Porzio William,
Barba Luisa,
Ahuja Rajeev
Publication year - 2021
Publication title -
advanced electronic materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.25
H-Index - 56
ISSN - 2199-160X
DOI - 10.1002/aelm.202001202
Subject(s) - materials science , pseudocapacitance , molecule , viologen , intercalation (chemistry) , dication , crystallography , photochemistry , chemistry , inorganic chemistry , supercapacitor , organic chemistry , electrode , electrochemistry
Using a combined theoretical and experimental approach, a mechanistic understanding of the interactions and pseudocapacitance of different quinone‐coupled viologen and pyridiniumium molecules sandwiched between titanium carbide (Ti 3 C 2 T x ) MXene layers has been provided. Three different derivatives of quinone‐coupled viologen and pyridiniumium are synthesized using nucleophilic substitution reaction and subsequently hybridized with Ti 3 C 2 T x MXene (organic@Ti 3 C 2 T x ) using self‐assembly approach. The atomic structure of pristine Ti 3 C 2 T x and organic@Ti 3 C 2 T x hybrid films is investigated using grazing incidence X‐ray diffraction and X‐ray pair distribution function analysis using synchrotron radiation. Spectroscopic results confirm the coupling of quinones with viologen and pyridiniumium molecules and their non‐covalent functionalization to the MXene without their catalytic decomposition. First‐principles calculations confirm that the preferred orientation of organic molecules upon intercalation/adsorption is horizontal to the Ti 3 C 2 T x surface. The authors reveal that these molecules attach to the Ti 3 C 2 T x surface with a significantly high binding energy (up to −2.77 eV) via a charge transfer mechanism. The electronic structure calculations show that all organic@Ti 3 C 2 T x hybrids preserved their metallic behavior. Free‐standing organic@Ti 3 C 2 T x hybrid films show a more than three times higher capacitance at ultra‐high scan rates (up to 20 V s −1 ) compared to their pristine counterpart due to molecular pillaring of organic molecules between Ti 3 C 2 T x layers via strong binding energies and charge transfer.