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Donor–Acceptor Metallopolymers Containing Ferrocene for Brain Inspired Memristive Devices
Author(s) -
Zhang Miaocheng,
Ma Chenxi,
Du Dawei,
Xiang Jing,
Yao Suhao,
Hu Ertao,
Liu Shujuan,
Tong Yi,
Wong WaiYeung,
Zhao Qiang
Publication year - 2020
Publication title -
advanced electronic materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.25
H-Index - 56
ISSN - 2199-160X
DOI - 10.1002/aelm.202000841
Subject(s) - memristor , materials science , nanotechnology , acceptor , optoelectronics , resistive random access memory , electrical conductor , ferrocene , inert , voltage , electrical engineering , electrode , electrochemistry , chemistry , physics , engineering , organic chemistry , condensed matter physics , composite material
To realize brain‐inspired devices and systems, memristor is one of the significant alternatives in breaking through the infrastructure restrictions of present logic and memory devices. Organic materials have become popular to fabricate memristive devices due to their unique properties of low cost, mechanical flexibility, and compatibility with complementary metal‐oxide‐semiconductor technology. Metallopolymer is a new kind of promising organic materials functioning as the resistive‐switching layers of memristive devices due to the unique donor–acceptor type structure, which performs good ability of tuning electron concentration to boost the migration of inner ions. Herein, a new metallopolymer MP1 containing ferrocene and triphenylamine is designed and synthesized, which is utilized as a resistive‐switching layer of memristor with active and inert electrodes of Ag and Pt, respectively. Process flow of devices is fully developed and MP1 is found to act as metal‐ions‐accommodation site with the great potential to boost the formation of conductive filaments in the active region. More interestingly, the conductance of Ag/MP1/Pt memristor can be modulated under various voltage pulses exhibiting distinguished electrical properties. Additionally, synaptic functions are successfully emulated using such MP1‐based memristors. This work will greatly expand the further development of organic memristors for flexible brain‐inspired systems.