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Investigation of Energy Levels and Crystal Structures of Cesium Lead Halides and Their Application in Full‐Color Light‐Emitting Diodes
Author(s) -
Van Le Quyet,
Park Minjoon,
Sohn Woonbae,
Jang Ho Won,
Kim Soo Young
Publication year - 2017
Publication title -
advanced electronic materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.25
H-Index - 56
ISSN - 2199-160X
DOI - 10.1002/aelm.201600448
Subject(s) - materials science , halide , perovskite (structure) , ion , crystal (programming language) , light emitting diode , crystal structure , analytical chemistry (journal) , crystallography , optoelectronics , chemistry , inorganic chemistry , organic chemistry , chromatography , computer science , programming language
Inorganic CsPbX 3 perovskites with compositions including CsPbBr x Cl 3− x , CsPbBr 3 , and CsPbBr x I 3− x are synthesized, and their properties are investigated. Tauc plots calculated from the UV–vis spectra of the materials show that the bandgaps of CsPbBr x Cl 3− x , CsPbBr 3 , and CsPbBr x I 3− x are 2.7, 2.35, and 1.8 eV, respectively. The as‐prepared CsPbX 3 nanodots have a cubic structure and their crystal sizes are around 5–10 nm. The diffraction peak intensity of the (110) plane is increased by adding Cl anion and reduced by adding I anion. By contrast, the peak intensity of the (200) plane is reduced by the introduction of Cl − ions and increased by the introduction of I − ions, suggesting that the nature of the halide anions affects the crystal orientation of CsPbX 3 quantum dots. The highest occupied molecular orbital/lowest unoccupied molecular orbital levels of CsPbBr x Cl 3− x , CsPbBr 3 , and CsPbBr x I 3− x calculated from ultraviolet photoemission spectra and UV–vis spectra are 6.5/3.8, 6.5/4.15, and 6.1/4.3 eV, respectively. The maximum luminance values measured for CsPbBr x Cl 3− x , CsPbBr 3 , and CsPbBr x I 3− x ‐based light‐emitting diodes (LEDs) are 15.2, 51.7, and 21.7 cd m −2 , respectively. This research provides an overview of the energy levels and crystal structures of CsPbX 3 quantum dots for the design of inorganic perovskite‐based LEDs with high luminance and power efficiencies.