Open AccessDesigning 3D Anode Based on Pore‐Size‐Dependent Li Deposition Behavior for Reversible Li‐Free All‐Solid‐State Batteries
Author(s) -
Park Se Hwan,
Jun Dayoung,
Lee Gyu Hyeon,
Lee Seong Gyu,
Jung Ji Eun,
Bae Ki Yoon,
Son Samick,
Lee Yun Jung
Publication year - 2022
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.202203130
Subject(s) - anode , electrolyte , materials science , cathode , faraday efficiency , deposition (geology) , chemical engineering , coating , porosity , layer (electronics) , composite material , electrode , chemistry , paleontology , sediment , biology , engineering
Li‐free all‐solid‐state batteries can achieve high energy density and safety. However, separation of the current collector/solid electrolyte interface during Li deposition increases interfacial resistance, which deteriorates safety and reversibility. In this study, a reversible 3D porous anode is designed based on Li deposition behavior that depends on the pore size of the anode. More Li deposits are accommodated within the smaller pores of the Li hosting anode composed of Ni particles with a granular piling structure; this implies the Li movement into the anode is achieved via diffusional Coble creep. Surface modification of Ni with a carbon coating layer and Ag nanoparticles further increases the Li hosting capacity and enables Li deposition without anode/solid electrolyte interface separation. A Li‐free all‐solid‐state full cell with a LiNi 0.8 Mn 0.1 Co 0.1 O 2 cathode shows an areal capacity of 2 mAh cm −2 for retaining a Coulombic efficiency of 99.46% for 100 cycles at 30 °C.