Open AccessPhosphorus/Phosphide‐Based Materials for Alkali Metal‐Ion Batteries
Author(s) -
Chen Fangzheng,
Xu Jie,
Wang Shanying,
Lv Yaohui,
Li Yang,
Chen Xiang,
Xia Ailin,
Li Yongtao,
Wu Junxiong,
Ma Lianbo
Publication year - 2022
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.202200740
Subject(s) - phosphide , phosphorus , volume expansion , anode , materials science , electrochemistry , gallium phosphide , alkali metal , nanotechnology , metal , chemistry , metallurgy , electrode , medicine , optoelectronics , organic chemistry
Phosphorus‐ and phosphide‐based materials with remarkable physicochemical properties and low costs have attracted significant attention as the anodes of alkali metal (e.g., Li, Na, K, Mg, Ca)‐ion batteries (AIBs). However, the low electrical conductivity and large volume expansion of these materials during electrochemical reactions inhibit their practical applications. To solve these problems, various promising solutions have been explored and utilized. In this review, the recent progress in AIBs using phosphorus‐ and phosphide‐based materials is summarized. Thereafter, the in‐depth working principles of diverse AIBs are discussed and predicted. Representative works with design concepts, construction approaches, engineering strategies, special functions, and electrochemical results are listed and discussed in detail. Finally, the existing challenges and issues are concluded and analyzed, and future perspectives and research directions are given. This review can provide new guidance for the future design and practical applications of phosphorus‐ and phosphide‐based materials used in AIBs.