Open AccessFluorine‐Driven Enhancement of Birefringence in the Fluorooxosulfate: A Deep Evaluation from a Joint Experimental and Computational Study
Author(s) -
Jin Wenqi,
Zhang Wenyao,
Tudi Abudukadi,
Wang Liying,
Zhou Xin,
Yang Zhihua,
Pan Shilie
Publication year - 2021
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.202003594
Subject(s) - birefringence , anisotropy , materials science , tetrahedron , optical anisotropy , optics , optoelectronics , band gap , crystallography , chemistry , physics
Understanding and exploring the functional modules (FMs) consisting of local atomic groups can promote the development of the materials with functional performances. Oxygen‐containing tetrahedral modules are popular in deep‐ultraviolet (DUV) optical materials, but their weak optical anisotropy is adverse to birefringence. Here, the fluorooxosulfate group is proved as a new birefringence‐enhanced FM for the first time. The birefringence of fluorooxosulfates can be 4.8–15.5 times that of sulfates with the same metal cations while maintaining a DUV band gap. The polarizing microscope measurement confirms the birefringence enhancement by using the millimeter crystals experimentally. The theoretical studies from micro and macro levels further reveal a novel universal strategy that the fluorine induced anisotropic electronic distribution in fluorooxo–tetrahedral group is responsible for the enhancement of birefringence. This study will guide the future discovery of DUV optical materials with enlarged birefringence.