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Microstructural Engineering of Cathode Materials for Advanced Zinc‐Ion Aqueous Batteries
Author(s) -
Pam Mei Er,
Yan Dong,
Yu Juezhi,
Fang Daliang,
Guo Lu,
Li Xue Liang,
Li Tian Chen,
Lu Xunyu,
Ang Lay Kee,
Amal Rose,
Han Zhaojun,
Yang Hui Ying
Publication year - 2021
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.202002722
Subject(s) - cathode , materials science , microstructure , electrochemistry , electrolyte , nanotechnology , surface engineering , chemical engineering , metallurgy , engineering , electrical engineering , electrode , chemistry
Zinc‐ion batteries (ZIBs) have attracted intensive attention due to the low cost, high safety, and abundant resources. However, up to date, challenges still exist in searching for cathode materials with high working potential, excellent electrochemical activity, and good structural stability. To address these challenges, microstructure engineering has been widely investigated to modulate the physical properties of cathode materials, and thus boosts the electrochemical performances of ZIBs. Here, the recent research efforts on the microstructural engineering of various ZIB cathode materials are mainly focused upon, including composition and crystal structure selection, crystal defect engineering, interlayer engineering, and morphology design. The dependency of cathode performance on aqueous electrolyte for ZIB is further discussed. Finally, future perspectives and challenges on microstructure engineering of cathode materials for ZIBs are provided. It is aimed to provide a deep understanding of the microstructure engineering effect on Zn 2+ storage performance.

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