Open AccessSurface Doping of Organic Single‐Crystal Semiconductors to Produce Strain‐Sensitive Conductive Nanosheets
Author(s) -
Watanabe Shun,
Hakamatani Ryohei,
Yaegashi Keita,
Yamashita Yu,
Nozawa Han,
Sasaki Mari,
Kumagai Shohei,
Okamoto Toshihiro,
Tang Cindy G.,
Chua LayLay,
Ho Peter K. H.,
Takeya Jun
Publication year - 2021
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.202002065
Subject(s) - dopant , materials science , chemical physics , doping , semiconductor , nanotechnology , crystal (programming language) , van der waals force , impurity , organic semiconductor , electrical conductor , optoelectronics , condensed matter physics , molecule , chemistry , organic chemistry , physics , computer science , composite material , programming language
A highly periodic electrostatic potential, even though established in van der Waals bonded organic crystals, is essential for the realization of a coherent band electron system. While impurity doping is an effective chemical operation that can precisely tune the energy of an electronic system, it always faces an unavoidable difficulty in molecular crystals because the introduction of a relatively high density of dopants inevitably destroys the highly ordered molecular framework. In striking contrast, a versatile strategy is presented to create coherent 2D electronic carriers at the surface of organic semiconductor crystals with their precise molecular structures preserved perfectly. The formation of an assembly of redox‐active molecular dopants via a simple one‐shot solution process on a molecularly flat crystalline surface allows efficient chemical doping and results in a relatively high carrier density of 10 13 cm −2 at room temperature. Structural and magnetotransport analyses comprehensively reveal that excellent carrier transport and piezoresistive effects can be obtained that are similar to those in bulk crystals.