Open AccessProgrammed Molecular Assembly of Abrupt Crystalline Organic/Organic Heterointerfaces Yielding Metal‐Organic Framework Diodes with Large On‐Off Ratios
Author(s) -
Chandresh Abhinav,
Liu Xiaojing,
Wöll Christof,
Heinke Lars
Publication year - 2021
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.202001884
Subject(s) - heterojunction , materials science , organic semiconductor , optoelectronics , diode , lattice constant , oled , epitaxy , organic electronics , anthracene , layer (electronics) , semiconductor , organic solar cell , nanotechnology , diffraction , chemistry , polymer , optics , organic chemistry , transistor , composite material , physics , voltage , quantum mechanics
Structurally well‐defined, crystalline organic/organic heterojunctions between C 60 ‐ and anthracene‐based semiconductors are realized via layer‐by‐layer deposition of metal‐organic framework, MOF, thin films. As demonstrated by X‐ray diffraction, perfect epitaxy is achieved by adjusting the lattice constants of the two different MOFs. Deposition of top electrodes allows to fabricate p–n as well as n–p devices. Measurements of the electrical properties reveal the presence of high‐performance diodes, with a current on/off ratio of up to 6 orders of magnitude and an ideality factor close to unity. The crystalline nature of the abrupt organic/organic heterojunction provides the basis for a rational, simulation‐based optimization and tailoring of such organic semiconductor interfaces.