Open AccessZnO–Ti 3 C 2 MXene Electron Transport Layer for High External Quantum Efficiency Perovskite Nanocrystal Light‐Emitting Diodes
Author(s) -
Lu Po,
Wu Jinlei,
Shen Xinyu,
Gao Xupeng,
Shi Zhifeng,
Lu Min,
Yu William W.,
Zhang Yu
Publication year - 2020
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.202001562
Subject(s) - materials science , light emitting diode , nanocrystal , perovskite (structure) , quantum efficiency , optoelectronics , nitride , diode , carbide , halide , layer (electronics) , nanotechnology , metallurgy , inorganic chemistry , crystallography , chemistry
2D transition metal carbides, nitrides, and carbonitrides called MXenes show outstanding performance in many applications due to their superior physical and chemical properties. Herein, a ZnO–MXene mixture with different contents of Ti 3 C 2 is applied as electron transport layers (ETLs) and the influence of the Ti 3 C 2 MXene in all‐inorganic metal halide perovskite nanocrystal light‐emitting diodes (perovskite NC LEDs) is explored. The addition of Ti 3 C 2 makes more balanced charge carrier transport in LEDs by changing the energy level structure and electron mobility of ETL. Moreover, lower surface roughness is obtained for the ETL, thus guaranteeing uniform distribution of the perovskite NCs layer and further reducing leakage current. As a result, a 17.4% external quantum efficiency (EQE) with low efficiency roll‐off is achieved with 10% Ti 3 C 2 , which is a 22.5% improvement compared to LEDs without Ti 3 C 2 .