Open AccessTunable Layered (Na,Mn)V 8 O 20 · n H 2 O Cathode Material for High‐Performance Aqueous Zinc Ion Batteries
Author(s) -
Du Min,
Liu Chaofeng,
Zhang Feng,
Dong Wentao,
Zhang Xiaofei,
Sang Yuanhua,
Wang JianJun,
Guo YuGuo,
Liu Hong,
Wang Shuhua
Publication year - 2020
Publication title -
advanced science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.388
H-Index - 100
ISSN - 2198-3844
DOI - 10.1002/advs.202000083
Subject(s) - cathode , materials science , aqueous solution , electrochemistry , manganese , ion , transition metal , electrical resistivity and conductivity , analytical chemistry (journal) , inorganic chemistry , electrode , metallurgy , chemistry , catalysis , electrical engineering , biochemistry , organic chemistry , chromatography , engineering
Rechargeable aqueous zinc‐ion batteries (ZIBs) show promise for use in energy storage. However, the development of ZIBs has been plagued by the limited cathode candidates, which usually show low capacity or poor cycling performance. Here, a reversible Zn//(Na,Mn)V 8 O 20 · n H 2 O system is reported, the introduction of manganese (Mn) ions in NaV 8 O 20 to form (Na,Mn)V 8 O 20 exhibits an outstanding electrochemical performance with a capacity of 377 mA h g −1 at a current density of 0.1 A g −1 . Through experimental and theoretical results, it is discovered that the outstanding performance of (Na,Mn)V 8 O 20 · n H 2 O is ascribed to the Mn 2+ /Mn 3+ ‐induced high electrical conductivity and Na + ‐induced fast migration of Zn 2+ . Other cathode materials derived from (Na,Mn)V 8 O 20 · n H 2 O by substituting Mn with Fe, Co, Ni, Ca, and K are explored to confirm the unique advantages of transition metal ions. With an increase in Mn content in NaV 8 O 20 , (Na 0.33 ,Mn 0.65 )V 8 O 20 · n H 2 O can deliver a reversible capacity of 150 mA h g −1 and a capacity retention of 99% after 1000 cycles, which may open new opportunities for the development of high‐performance aqueous ZIBs.